at Google ScholarTitle data
Schwob, Tobias ; Ade, Mirco ; Kempe, Rhett:
A Cobalt Catalyst Permits the Direct Hydrogenative Synthesis of 1H‐Perimidines from a Dinitroarene and an Aldehyde.
In: ChemSusChem.
Vol. 12
(2019)
Issue 13
.
- pp. 3013-3017.
ISSN 1864-564X
DOI: https://doi.org/10.1002/cssc.201900498
Abstract in another language
A new sustainable catalytic reaction, the synthesis of 1H‐ perimidines from a dinitroarene and an aldehyde in the presence of H2, was achieved. An earth‐abundant metal catalyst was developed to permit the efficient, highly chemoselective, and consecutive hydrogenation of dinitroarenes. The catalyst was reusable and easy to handle. The use of a specific Co complex and its pyrolysis at a certain temperature was crucial to achieve high activity for the complex organic transformation. Benzylic and aliphatic aldehydes could undergo the hydrogenative condensation, and many functional groups, including hydrogenation‐sensitive examples such as iodo aryl, nitrile, olefin, and alkyne groups, were tolerated.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Additional notes: | Special Issue: Sustainable Organic Synthesis |
| Keywords: | Cobalt; Dinitroarenes; Hydrogenation; Perimidines; Pyrolysis |
| Institutions of the University: | Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science 500 Science > 540 Chemistry |
| Date Deposited: | 16 Mar 2021 07:57 |
| Last Modified: | 31 Jan 2022 10:15 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/63966 |