at Google ScholarTitle data
Beerwerth, Joachim ; Bojer, Beate ; Senker, Jürgen ; Böhmer, Roland:
Time Scales of the Quasitetrahedral Motion in KMnO₄ Observed by ¹⁷O Central-Transition NMR Spectroscopy.
In: The Journal of Physical Chemistry C.
Vol. 124
(2020)
Issue 29
.
- pp. 16202-16208.
ISSN 1932-7455
DOI: https://doi.org/10.1021/acs.jpcc.0c04704
Abstract in another language
Oxygen-17 spin relaxation and stimulated-echo experiments are carried out to study temperature-dependent reorientational time scales in potassium permanganate. From an analysis of the present data, an energy barrier of 0.35 eV is found. This activation energy is much larger than the one reported previously (Jakobsen et al. Quantitative Dynamics and Structure for Crystalline Cs2WO4 and KMnO4 Determined from High-Field O-17 Variable-Temperature MAS NMR Experiments, J. Phys. Chem. C 2014, 118, 20639-20646), but it is on the order of magnitude expected from observations for the dynamics of other tetraoxoanions in ionic crystals. The various contributions to the measured spin relaxation times and details regarding the two-time correlation functions for KMnO4 are discussed.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Additional notes: | ISI:000555507000058 |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry III Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry III > Chair Inorganic Chemistry III - Univ.-Prof. Dr. Jürgen Senker Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science 500 Science > 540 Chemistry |
| Date Deposited: | 17 Mar 2021 07:58 |
| Last Modified: | 06 Jul 2023 13:44 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/64016 |