Title data
Bringmann, Gerhard ; Breuning, Matthias ; Pfeifer, Robert-Michael ; Schreiber, Petra:
Atropo-enantioselective synthesis of a C₃-symmetric tripodal ligand with three axially chiral biaryl subunits.
In: Tetrahedron: Asymmetry.
Vol. 14
(2003)
Issue 15
.
- pp. 2225-2228.
ISSN 0957-4166
DOI: https://doi.org/10.1016/S0957-4166(03)00406-3
Abstract in another language
In contrast to the numerous successful applications of C2-symmetric biaryls as powerful tools for asymmetric synthesis, there have so far been only few reports on combinations of C3-symmetry with axial chirality. We present here the first enantioselective synthesis of a novel family of tripodal ligands containing three axially chiral biaryl subunits in an (M,M,M)- or, optionally, (P,P,P)-configured form. The incorporation of a PCl2- and a TiCl-fragment into the central cavity was achieved.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Organic Chemistry > Professor Organic Chemistry - Univ.-Prof. Dr. Matthias Breuning Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Organic Chemistry |
Result of work at the UBT: | No |
DDC Subjects: | 500 Science > 540 Chemistry |
Date Deposited: | 12 Jan 2022 09:31 |
Last Modified: | 12 Jan 2022 09:31 |
URI: | https://eref.uni-bayreuth.de/id/eprint/68332 |