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Lewis acid-catalyzed Beckmann rearrangement of ketoximes in ionic liquids

Title data

Zicmanis, Andris ; Katkevica, Sarmite ; Mekss, Peteris:
Lewis acid-catalyzed Beckmann rearrangement of ketoximes in ionic liquids.
In: Catalysis Communications. Vol. 10 (2009) Issue 5 . - pp. 614-619.
ISSN 1566-7367
DOI: https://doi.org/10.1016/j.catcom.2008.11.008

Abstract in another language

The Beckmann rearrangement of five ketoximes was done in 17 different ionic liquids by using four Lewis acids. The effect of the type of cation and the type of anion in the ionic liquid on the rate of the rearrangement reaction and product composition is compared and discussed. The effects of the hydrophobicity and the hydrogen bonding ability of ionic liquids on the rearrangement of ketoximes were investigated, as well as the catalytical activity of the Lewis acids.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Ionic liquids; Beckmann rearrangement; Lewis acids
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology > Chair Animal Ecology I
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 14 Dec 2022 09:12
Last Modified: 14 Dec 2022 09:12
URI: https://eref.uni-bayreuth.de/id/eprint/73021