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Repulsive Osmotic Delamination : 1D Dissolution of 2D Materials

Title data

Dudko, Volodymyr ; Khoruzhenko, Olena ; Weiß, Sebastian ; Daab, Matthias ; Loch, Patrick ; Schwieger, Wilhelm ; Breu, Josef:
Repulsive Osmotic Delamination : 1D Dissolution of 2D Materials.
In: Advanced Materials Technologies. Vol. 8 (2023) Issue 3 . - 2200553.
ISSN 2365-709X
DOI: https://doi.org/10.1002/admt.202200553

Official URL: Volltext

Abstract in another language

2D materials have proved their potential in nearly every area of material science and chemistry. Unfortunately, large-scale production of nanosheets is not straightforward. Current methods suffer from low yield, uncontrollable defects, and requires a high-energy input. There is always a tradeoff between high quality and high yield. In this review, the alternative is highlighted to existing methods of 2D nanosheet production - 1D dissolution, historically known as osmotic swelling. As a thermodynamically driven, and therefore spontaneous, process it provides numerous benefits such as high aspect ratio and defect-free nanosheets with a quantitative yield. In this review, the theory behind this process is discussed, compare it with the existing methods, and highlight the key features that allow to extend 1D dissolution to different charged layered materials. Moreover, the applications in which nanosheets obtained by 1D dissolution proved to be advantageous due to their unique, processing-related features are discussed.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: 2-DIMENSIONAL MATERIALS; CRYSTAL-STRUCTURE; NANOCOMPOSITE HYDROGELS; NANOSHEETs CRYSTALLITES; HYDROXIDE NANOSHEETS; ELECTRON-MICROSCOPY; LAYERED SILICATES; BARRIER COATINGS; EXFOLIATION; GRAPHENE
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I > Chair Inorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 06 Apr 2023 06:50
Last Modified: 29 Jan 2024 06:47
URI: https://eref.uni-bayreuth.de/id/eprint/75845