at Google ScholarTitle data
Loch, Patrick ; Martin, Thomas ; Grüner, Michael ; Kaupp, Günther ; Schwieger, Wilhelm ; Breu, Josef:
Synthesis of Large Platelets of Egyptian Blue via Pseudomorphosis after NaRUB-18.
In: Zeitschrift für anorganische und allgemeine Chemie.
Vol. 646
(2020)
Issue 18
.
- pp. 1570-1574.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.202000203
Abstract in another language
A colored platy substrate with appreciable aspect ratio can improve the hiding power while extending the color range of pearlescent pigments. One of the oldest synthetic pigments, Egyptian blue, possesses a layered structure and a platy morphology, making it a promising colored substrate for pearlescent pigments, which derives its blue color from Cu-II. Unfortunately, existing synthesis routes are either not technically benign or lack the natural platy morphology. Here, we introduce a new synthesis route starting with large, square-shaped platelets of a synthetic layered sodium silicate (NaRUB-18). As evidenced by Rietveld refinement and scanning electron microscopy, NaRUB-18 can be converted with conservation of this attractive morphology (pseudomorphosis) into Egyptian blue.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Egyptian blue; Solid state synthesis; Pseudomorphosis; NaRUB-18; Layered silicic acid; TOPOTACTIC CONDENSATION; CRYSTAL-STRUCTURE; LAYER SILICATES; ZEOLITE; PIGMENTS; CONVERSION; KANEMITE; SODIUM; COPPER; RWR |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I > Chair Inorganic Chemistry I - Univ.-Prof. Dr. Josef Breu |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 06 Apr 2023 06:22 |
| Last Modified: | 06 Apr 2023 06:22 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/75859 |