at Google ScholarTitle data
Riemer, Daniel ; Schilling, Waldemar ; Goetz, Anne ; Zhang, Yu ; Gehrke, Sascha ; Tkach, Igor ; Hollóczki, Oldamur ; Das, Shoubhik:
CO₂-Catalyzed Efficient Dehydrogenation of Amines with Detailed Mechanistic and Kinetic Studies.
In: ACS Catalysis.
Vol. 8
(2018)
Issue 12
.
- pp. 11679-11687.
ISSN 2155-5435
DOI: https://doi.org/10.1021/acscatal.8b03059
Abstract in another language
CO2-catalyzed dehydrogenation of amines has been achieved under photocatalytic conditions. With this concept, various amines have been selectively dehydrogenated to the corresponding imines in the presence of different functional groups such as nitrile, nitro, ester, halogen, ether, thioether, and carbonyl or carboxylic acid moieties. At the end, the CO2-catalyzed synthesis of pharmaceutical drugs has been achieved. The CO2 radical has been detected by EPR spectroscopy using DMPO, and the mechanism of this reaction is proposed on the basis of DFT calculations and experimental evidence.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry I > Chair Organic Chemistry I - Univ.-Prof. Dr. Das Shoubhik Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry I |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 19 Jul 2023 11:57 |
| Last Modified: | 08 Nov 2023 11:23 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/86199 |