at Google ScholarTitle data
Riemer, Daniel ; Mandaviya, Bhavdip ; Schilling, Waldemar ; Götz, Anne Charlotte ; Kühl, Torben ; Finger, Markus ; Das, Shoubhik:
CO₂-Catalyzed Oxidation of Benzylic and Allylic Alcohols with DMSO.
In: ACS Catalysis.
Vol. 8
(2018)
Issue 4
.
- pp. 3030-3034.
ISSN 2155-5435
DOI: https://doi.org/10.1021/acscatal.7b04390
Abstract in another language
CO2-catalyzed transition-metal-free oxidation of alcohols has been achieved. Earlier, several methodologies have been explored for alcohol oxidations based on transition-metal catalysts. However, owing to the cheaper price, easy separation and nontoxicity, transition-metal-free systems are in high demand to the pharmaceutical industries. For this reason, various primary and secondary alcohols have been selectively oxidized to the corresponding carbonyl compounds using CO2 as a catalyst in the presence of different functional groups such as nitrile, nitro, aldehyde, ester, halogen, ether, and so on. At the end, transition-metal-free syntheses of pharmaceuticals have also been achieved. Finally, the role of CO2 has been investigated in detail, and the mechanism is proposed on the basis of experiments and DFT calculations.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | CO2; alcohols; carbonyl compounds; oxidations; pharmaceuticals |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry I > Chair Organic Chemistry I - Univ.-Prof. Dr. Das Shoubhik Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry I |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 19 Jul 2023 11:33 |
| Last Modified: | 08 Nov 2023 11:23 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/86203 |