at Google ScholarTitle data
Butovskii, Mikhail V. ; Döring, Christian ; Bezugly, Viktor ; Wagner, Frank R. ; Grin, Yuri ; Kempe, Rhett:
Molecules containing rare-earth atoms solely bonded by transition metals.
In: Nature Chemistry.
Vol. 2
(2010)
Issue 9
.
- pp. 741-744.
ISSN 1755-4349
DOI: https://doi.org/10.1038/nchem.718
Abstract in another language
Although metal-metal bonding is important in the chemistry of both solid-state intermetallic compounds and molecular species, the study of this bonding is limited by the compounds available and it is rarely possible to identify connections between these two areas. In this study, molecular intermetalloids Ln(ReCp(2))(3) (Ln = Sm, Lu and La) have been synthesized that contain lanthanoid metals bound only to transition metals. Although they are highly reactive species, such lanthanoid-core transition-metal-shell compounds can be stable in solution. They mimic the bonding situation of intermetallic compounds, as revealed by a direct comparison of molecular and solid state lanthanoid-transition metal bonding.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Cyclopentanes/chemical synthesis/chemistry; Lanthanum/chemistry; Lutetium/chemistry; Magnetic Resonance Spectroscopy; Models, Molecular; Organometallic Compounds/chemical synthesis/chemistry; Quantum Theory; Rhenium/chemistry; Samarium/chemistry |
| Institutions of the University: | Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science 500 Science > 540 Chemistry |
| Date Deposited: | 23 Mar 2015 06:36 |
| Last Modified: | 15 Dec 2017 08:05 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/8757 |