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High and Tuneable Anisotropic Thermal Conductivity Controls the Temperature Distribution of 3D Printed All-Polyethylene Objects

Title data

Klein, Ina ; Tran, Thomas ; Reiser, René ; Theis, Maximilian ; Rosenfeldt, Sabine ; Schöttle, Marius ; Schirmeister, Carl ; Bösecke, Peter ; Rettinger, Stefan ; Mühlhaupt, Rolf ; Retsch, Markus:
High and Tuneable Anisotropic Thermal Conductivity Controls the Temperature Distribution of 3D Printed All-Polyethylene Objects.
In: Journal of Materials Chemistry A. Vol. 11 (2023) Issue 41 . - pp. 22492-22502.
ISSN 2050-7496
DOI: https://doi.org/10.1039/d3ta04483a

Project information

Project title:
Project's official title
Project's id
Integriertes Graduiertenkolleg „Transport in strukturierten Materialien“ (MGK)
492723217

Project financing: Deutsche Forschungsgemeinschaft

Abstract in another language

With ongoing miniaturization and weight reduction of portable electronic devices, effective heat dissipation is essential to inhibit malfunctions and premature failure. The application of fillers in a polymer matrix enhances the thermal conductivity of lightweight materials but impedes recyclability. All-polyethylene (all-PE) materials represent a sustainable and easy-to-recycle single-material alternative, whereby high and tunable thermal conductivity is provided by process-induced hierarchical PE nanostructures. Essential for this type of composite-free high-performance material is the specific PE composition containing high amounts of ultra-high molecular weight PE that form ultrastrong extended-chain nanostructures induced by shear and elongational flow during processing. This results in self-reinforcing fibre-like shish-kebab nanostructures with a high thermal conductivity parallel to the extended PE chains. Extrusion-based 3D printing enables tuning the orientation of the PE nanostructure to tailor the orientation and magnitude of the thermal conductivity. Thus, this material class highlights the possibility of combining digitally programmable heat management in 3D printed materials with sustainable material concepts.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry I > Chair Physical Chemistry I - Univ.-Prof. Dr. Markus Retsch
Research Institutions
Research Institutions > Affiliated Institutes
Research Institutions > Affiliated Institutes > Bavarian Polymer Institute (BPI)
Research Institutions > Collaborative Research Centers, Research Unit > SFB 1585 - MultiTrans – Structured functional materials for multiple transport in nanoscale confinements
Research Institutions > Collaborative Research Centers, Research Unit
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 24 Nov 2023 07:13
Last Modified: 06 Feb 2024 05:58
URI: https://eref.uni-bayreuth.de/id/eprint/87858