at Google ScholarTitle data
Ziegenbalg, Nicole ; Elbinger, Lada ; Schubert, Ulrich S. ; Brendel, Johannes C.:
Polymers from S-vinyl monomers : reactivities and properties.
In: Polymer Chemistry.
Vol. 13
(2022)
Issue 35
.
- pp. 5019-5041.
ISSN 1759-9954
DOI: https://doi.org/10.1039/D2PY00850E
Abstract in another language
The large variety of available functional groups, their versatility, and the various polymerization techniques have made vinyl monomers the prevalent source for preparation of polymers. Interestingly, among this wide variety of applied structures S-vinyl monomers have remained a niche for the last decades despite their unique set of properties and early reports on their reactivities. An obstacle has been the limited access on a technical scale, but recent developments in sulfur chemistry and the request for more diverse reactivities might lead to a renaissance of these often neglected compounds. In particular, the different variations of sulfur moieties and the correlating diversity of properties render these compounds increasingly attractive for fundamental research as well as applications. A challenge, however, remains the detailed understanding and control of their polymerization behavior, as these S-vinyl compounds might be prone to side reactions depending on the applied reactions. In this regard, this review intends to provide a comprehensive overview of reported polymerization techniques, their challenges and limitations with regard to the sulfur compounds, and the resulting reactivities of the corresponding monomers in homopolymerizations but as well copolymerizations with various other vinyl monomers. We further include reports on characteristic properties and tried to highlight some potential applications of the resulting polymers. Considering the various modifications of sulfur, we distinguished according to electron rich S-vinyl monomers, such as vinyl sulfides and electron deficient compounds including the various oxidized variants. In accordance, the reactivities differ significantly and suitable polymerization techniques are summarized for each class of monomers.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I > Chair Macromolecular Chemistry I - Univ.-Prof. Dr. Johannes C. Brendel |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 20 Feb 2024 12:12 |
| Last Modified: | 02 May 2024 07:39 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/88629 |