at Google ScholarTitle data
Sila, Niko ; Dürrmann, Andreas ; Weber, Birgit ; Heinemann, Frank W. ; Irrgang, Torsten ; Kempe, Rhett:
A Selective Iron(I) Hydrogenation Catalyst.
In: Journal of the American Chemical Society.
(September 2024)
.
ISSN 1520-5126
DOI: https://doi.org/10.1021/jacs.4c07959
Abstract in another language
Iron is the most abundant transition metal of the Earth’s crust, and the understanding of its function in key technologies, such as catalysis, is highly important. We report here on an iron(I) hydrogenation catalyst. Our catalyst activates hydrogen via heterolytic bond cleavage, forms a monohydride, and hydrogenates polar double bonds via a bimetallic pathway (potassium-assisted hydride transfer). The mechanism observed seems to exclude oxidative addition and reductive elimination pathways, permitting the tolerance of numerous hydrogenation-sensitive functional groups, as demonstrated for the hydrogenation of C═O bonds.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science 500 Science > 540 Chemistry |
| Date Deposited: | 26 Sep 2024 05:26 |
| Last Modified: | 26 Sep 2024 06:48 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/90481 |