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Facile large-scale synthetic route to monodisperse ZnO nanocrystals
Title data
Ehlert, Sascha P. ; Lunkenbein, Thomas ; Breu, Josef ; Förster, Stephan:
Facile large-scale synthetic route to monodisperse ZnO nanocrystals.
In: Colloids and Surfaces A: Physicochemical and Engineering Aspects.
Vol. 444
(2014)
.
- pp. 76-80.
ISSN 0927-7757
DOI: https://doi.org/10.1016/j.colsurfa.2013.12.034
Abstract in another language
We report an efficient, robust and up-scalable synthetic route to small, spherical, well stabilized, narrow disperse, crystalline ZnO nanoparticles. The synthesis utilizes Zn-oleate or Zn-stearate as precursors, which are hydrolyzed in polar organic solvents to obtain ZnO nanoparticles in diameters in the range of 3–5 nm on multi-gram scales. The synthesis exploits the use of oleates and stearates as good precursors and stabilizing agents together with the hydrolysis route to obtain small ZnO nanoparticles in a well-controlled way. The nanoparticles show the characteristic bright green fluorescence emission, and can be precipitated, dried, and redispersed in common organic solvents without aggregation. Because of their good steric stabilization and hydrophobic coating, these nanoparticles are very suitable for applications in polymer nanocomposites for UV-absorption and opto-electronic applications.
Further data
| Item Type: |
Article in a journal
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| Refereed: |
Yes |
| Additional notes: |
WOS:000333000800011
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| Keywords: |
Zinc oxide; Nanoparticles; Large-scale synthesis
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| Institutions of the University: |
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry I - Kolloidale Strukturen und Energiematerialien Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Colloids for Electrochemical Energy storage > Chair Chair Inorganic Colloids for Electrochemical Energy storage - Univ.-Prof. Dr. Josef Breu Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP A 2 Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP A 7 Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Colloids for Electrochemical Energy storage Research Institutions Research Institutions > Collaborative Research Centers, Research Unit Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Operando-Analytics of Electrochemical Energy Storage > Chair Operando-Analytics of Electrochemical Energy Storage - Univ.-Prof. Dr. Thomas Lunkenbein Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Operando-Analytics of Electrochemical Energy Storage |
| Result of work at the UBT: |
Yes |
| DDC Subjects: |
500 Science > 540 Chemistry |
| Date Deposited: |
20 Mar 2018 10:13 |
| Last Modified: |
04 Jul 2025 11:32 |
| URI: |
https://eref.uni-bayreuth.de/id/eprint/9252 |
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