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Intermolecular amination of ethyl benzo ylacetate via photocatalytic nitrene transfer reactions

Title data

Guo, Yujing ; Guo, Yifan ; Ding, Luyao ; Shi, Linlin ; Hao, Xinqi ; Koenigs, Rene M.:
Intermolecular amination of ethyl benzo ylacetate via photocatalytic nitrene transfer reactions.
In: Organic Chemistry Frontiers. Vol. 12 (2025) . - pp. 1612-1618.
ISSN 2052-4129
DOI: https://doi.org/10.1039/D4QO02194K

Abstract in another language

In this study, we report on a C–H functionalization of 1,3-dicarbonyl compounds via a photocatalytic nitrene transfer reaction. A wide range of 1,3-dicarbonyl substrates and iodinanes were found compatible with the reaction conditions to directly afford the C–H functionalization products without the need of preformation of nucleophilic enolate equivalents. Additionally, a comprehensive series of synthetic applications and control experiments were conducted, thereby further extending the practical utility of this approach.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 28 Mar 2025 07:29
Last Modified: 28 Mar 2025 07:29
URI: https://eref.uni-bayreuth.de/id/eprint/93016