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Photochemical α-amination of carbonyl groups with iodinanes

Title data

He, Suyuan ; Feng, Boya ; Tang, Yiben ; Chen, Ruiping ; Guo, Yujing ; Koenigs, Rene M.:
Photochemical α-amination of carbonyl groups with iodinanes.
In: Chemical Communications. Vol. 60 (2024) . - pp. 10128-10131.
ISSN 1364-548X
DOI: https://doi.org/10.1039/D4CC03564J

Abstract in another language

We report on a photochemical reaction of silyl enol ethers with iminoiodinanes. This aza Rubottom reaction provides a direct access towards α-amino carbonyl compounds under catalyst free reaction conditions with light as the sole source of energy. Control experiments suggest the participation of triplet nitrene intermediates.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 28 Mar 2025 09:02
Last Modified: 28 Mar 2025 09:02
URI: https://eref.uni-bayreuth.de/id/eprint/93028