at Google ScholarTitle data
Zhao, Xuemei ; Tang, Zhiyuan ; Shi, Linlin ; Guo, Yujing ; Koenigs, Rene M. ; Hao, Xinqi:
Photochemical nitrene transfer reactions of iminoiodinanes with sulfoxides.
In: Green Synthesis and Catalysis.
(2024)
.
ISSN 2666-5549
DOI: https://doi.org/10.1016/j.gresc.2024.05.001
Abstract in another language
Nitrene, as an important and intriguing versatile synthon, is widely utilized for the formation of diverse nitrogenous skeletons under thermal or photochemical conditions. Typically, the N-sulfonyl nitrenes could be smoothly generated from iminoiodinanes at relatively low reaction temperatures to generate N-sulfonyl nitrenes. Herein, we described the direct immidation reaction of iminoiodinanes with sulfoxides through a blue-light-induced nitrenes transfer process. This strategy offers an efficient and gentle pathway for directly obtaining sulfoximines within a reaction time of only 10 min. Moreover, the reaction conditions do not necessitate the exclusion of moisture or air, rendering this photocatalytic amination reaction highly practical. A broad range of iminoiodinanes were well tolerated and reacted with sulfoxides smoothly to give the corresponding products in moderate to good yields, which provides a practical and green protocol to access N-sulfonyl architectures.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Nitrene transfer; Photocatalysis; Amination reaction; N-sulfonyl architectures |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 28 Mar 2025 09:09 |
| Last Modified: | 28 Mar 2025 09:09 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93030 |