at Google ScholarTitle data
Bopape, Karabo M. ; Shah, Aryan ; Koenigs, Rene M.:
Photocatalytic [2,3]-Sigmatropic Rearrangement Reactions of Ethyl Diazoacetate.
In: Synlett.
Vol. 35
(2024)
.
- pp. 993-996.
ISSN 1437-2096
DOI: https://doi.org/10.1055/a-2201-7197
Abstract in another language
We describe a photocatalytic reaction of diazo compounds with allyl sulfides under visible-light reaction conditions. In the presence of Ru(bpy)3Cl2 as a photocatalyst, a [2,3]-sigmatropic rearrangement reaction occurs that leads to the formation of homoallylic sulfides. This reaction proceeds in acetone as the solvent, which is unusual in carbene-transfer reactions, and it shows a broad substrate scope in the rearrangement reaction of allylic sulfides.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | diazo compounds; photocatalysis; carbenes; rearrangement; homoallylic sulfides; allylic sulfides |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 28 Mar 2025 09:18 |
| Last Modified: | 28 Mar 2025 09:18 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93032 |