at Google ScholarTitle data
Zhu, Siqi ; Li, Fang ; Empel, Claire ; Jana, Sripati ; Pei, Chao ; Koenigs, Rene M.:
Furan Synthesis via Triplet Sensitization of Acceptor/Acceptor Diazoalkanes.
In: Advanced Synthesis & Catalysis.
Vol. 364
(2022)
.
- pp. 3149-3154.
ISSN 1615-4169
DOI: https://doi.org/10.1002/adsc.202200654
Abstract in another language
Herein, we report on the photocatalytic reaction of acceptor/acceptor diazoalkanes with terminal alkynes. Experimental and computational studies suggest the formation of a key triplet carbene intermediate that undergoes an addition reaction to the alkyne followed by cyclization to give furan heterocycles (31 to 90% yield). This reaction was studied with a broad range of alkynes and acceptor/acceptor diazoalkanes and now provides access to furans under mild reaction conditions.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 31 Mar 2025 13:34 |
| Last Modified: | 07 Oct 2025 10:56 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93085 |