at Google ScholarTitle data
Pei, Chao ; Yang, Zhen ; Koenigs, Rene M.:
Photochemical palladium-catalyzed methylation and alkylation reactions in cascade reactions of isonitriles.
In: Tetrahedron.
Vol. 123
(2022)
.
- 132939.
ISSN 0040-4020
DOI: https://doi.org/10.1016/j.tet.2022.132939
Abstract in another language
Photochemistry of palladium catalysis has been proved as an efficient strategy for cross coupling and multifunctionalization reaction of olefins via alkyl radicals. Herein, we demonstrate that isonitriles can serve as radical acceptors, which engage in a further radical cascade cyclization to furnish phenanthridine derivatives. We have also extended this photocatalytic process to cascade methylation reaction in one-pot with TMSCH2I as the radical precursor. Further experimental and computational studies indicate an intramolecular single electron transfer process to obtain alkyl radicals is involved in this transformation.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 31 Mar 2025 13:56 |
| Last Modified: | 14 May 2025 07:54 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93087 |