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Silver-Catalyzed N–H Functionalization of Aryl/Aryl Diazoalkanes with Anilines

Title data

He, Feifei ; Empel, Claire ; Koenigs, Rene M.:
Silver-Catalyzed N–H Functionalization of Aryl/Aryl Diazoalkanes with Anilines.
In: Organic Letters. Vol. 23 (2021) . - pp. 6719-6723.
ISSN 1523-7052
DOI: https://doi.org/10.1021/acs.orglett.1c02289

Abstract in another language

Herein, we report on the N–H functionalization reaction of primary and secondary anilines with diaryldiazoalkanes using simple AgPF6 as catalyst. We demonstrated broad applicability in the reaction of diaryldiazoalkanes with different anilines (31 examples, up to 97% yield). Furthermore, we propose a possible reaction mechanism for the N–H functionalization.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 01 Apr 2025 11:23
Last Modified: 07 Oct 2025 11:00
URI: https://eref.uni-bayreuth.de/id/eprint/93111