Title data
He, Feifei ; Koenigs, Rene M.:
Borane-Catalyzed Carbazolation Reactions of Aryldiazoacetates.
In: Organic Letters.
Vol. 23
(2021)
.
- pp. 5831-5835.
ISSN 1523-7052
DOI: https://doi.org/10.1021/acs.orglett.1c01982
Abstract in another language
Herein, we report on the tris(pentafluorophenyl)borane-catalyzed reaction of carbazole heterocycles with aryldiazoacetates. We could demonstrate that selective N–H functionalization occurs in the case of an unprotected carbazole, other N-heterocycles, and secondary amines in good yields. In contract, the protected carbazole undergoes C–H functionalization at the C-3 position in a good yield. The application of both approaches was studied in 41 examples with up to a 97% yield.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 01 Apr 2025 11:26 |
| Last Modified: | 14 May 2025 07:54 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93112 |

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