Title data
Empel, Claire ; Nguyen, Thanh Vinh ; Koenigs, Rene M.:
Tropylium-Catalyzed O–H Insertion Reactions of Diazoalkanes with Carboxylic Acids.
In: Organic Letters.
Vol. 23
(2021)
.
- pp. 548-553.
ISSN 1523-7052
DOI: https://doi.org/10.1021/acs.orglett.0c04069
Abstract in another language
Herein, we describe the application of a nonbenzenoid aromatic carbocation, namely tropylium, as an organic Lewis acid catalyst in O–H functionalization reactions of diazoalkanes with benzoic acids. The newly developed protocol is applicable to a wide range of diazoalkane and carboxylic acid substrates with excellent efficiency (43 examples, up to 99% yield).
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 01 Apr 2025 11:49 |
| Last Modified: | 07 Oct 2025 10:59 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93118 |

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