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Photochemical O−H Functionalization Reactions of Cyclic Diazoamides

Title data

Empel, Claire ; Verspeek, Dennis ; Jana, Sripati ; Koenigs, Rene M.:
Photochemical O−H Functionalization Reactions of Cyclic Diazoamides.
In: Advanced Synthesis & Catalysis. Vol. 362 (2020) . - pp. 4716-4722.
ISSN 1615-4169
DOI: https://doi.org/10.1002/adsc.202000818

Abstract in another language

Herein, we describe the photochemical O−H functionalization reaction of acidic alcohols with cyclic diazoamides. We studied the O−H functionalization reaction of different fluorinated and non-fluorinated alcohols to give the corresponding ether products in high yields (43 examples, up to 97% yield). Furthermore, we performed studies to evaluate a photoexcited proton transfer reaction pathway in comparison to classic carbene transfer reactions.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 01 Apr 2025 13:45
Last Modified: 07 Oct 2025 11:04
URI: https://eref.uni-bayreuth.de/id/eprint/93133