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Substrate‐Controlled Cyclopropanation Reactions of Glycals with Aryl Diazoacetates

Title data

Guo, Yujing ; Pei, Chao ; Koenigs, Rene M.:
Substrate‐Controlled Cyclopropanation Reactions of Glycals with Aryl Diazoacetates.
In: ChemCatChem. Vol. 12 (2020) . - pp. 4014-4018.
ISSN 1867-3899
DOI: https://doi.org/10.1002/cctc.202000569

Abstract in another language

Cyclopropanation reactions of d-glucal and d-galactal derivatives with aryldiazoacetates can be conducted in a substrate-controlled, stereoselective fashion using simple Rh(II) catalysts, which is further supported by DFT studies. Following this methodology, sugar-derived, donor-acceptor cyclopropanes can be accessed that allow stereoselective O-glycosylation reactions.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 02 Apr 2025 08:01
Last Modified: 14 May 2025 07:54
URI: https://eref.uni-bayreuth.de/id/eprint/93139