at Google ScholarTitle data
He, Feifei ; Li, Fang ; Koenigs, Rene M.:
Metal-Free Insertion Reactions of Silanes with Aryldiazoacetates.
In: The Journal of Organic Chemistry.
Vol. 85
(2020)
.
- pp. 1240-1246.
ISSN 1520-6904
DOI: https://doi.org/10.1021/acs.joc.9b02605
Abstract in another language
Si–H insertion reactions represent an important method for the efficient construction of new C–Si bonds, and typically, they are conducted in the presence of metal catalysts. In this report, we describe a photochemical approach that now allows the insertion of carbenes into the Si–H bond of silanes under metal-free reaction conditions (23 examples, up to 83% yield).
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 02 Apr 2025 09:10 |
| Last Modified: | 14 May 2025 07:54 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93145 |