at Google ScholarTitle data
Hommelsheim, Renè ; Guo, Yujing ; Yang, Zhen ; Empel, Claire ; Koenigs, Rene M.:
Blue‐Light‐Induced Carbene‐Transfer Reactions of Diazoalkanes.
In: Angewandte Chemie International Edition.
Vol. 58
(2019)
.
- pp. 1203-1207.
ISSN 1521-3773
DOI: https://doi.org/10.1002/anie.201811991
Abstract in another language
Carbenes are very important reactive intermediates to access a variety of complex molecules and are applied widely in organic synthesis and drug discovery. Typically, their chemistry is accessed by the use of transition metal catalysts. Herein, we describe the application of low-energy blue light for the photochemical generation of carbenes from donor–acceptor diazoalkanes. This catalyst-free and operationally simple approach enables highly efficient cyclopropenation reactions with alkynes and the rearrangement of sulfides under mild reaction conditions, which can be utilized for both batch and continuous-flow processes.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Additional notes: | Selected as a Hot Paper by the Editors |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 02 Apr 2025 12:14 |
| Last Modified: | 08 Oct 2025 06:57 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93164 |