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Visible Light Induced Metal-Free Carbene N-Carbazolation

Title data

Empel, Claire ; Patureau, Frederic W. ; Koenigs, Rene M.:
Visible Light Induced Metal-Free Carbene N-Carbazolation.
In: The Journal of Organic Chemistry. Vol. 84 (2019) . - pp. 11316-11322.
ISSN 1520-6904
DOI: https://doi.org/10.1021/acs.joc.9b01753

Abstract in another language

Metal-free N–H functionalization reactions represent an important strategy for sustainable C–N coupling reactions. In this report, we describe the visible light photolysis of aryl diazoacetates in the presence of some N-heterocycles that enables mild, metal-free N–H functionalization reactions of carbazole and azepine heterocycles (15 examples, up to 83% yield).

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 02 Apr 2025 12:28
Last Modified: 07 Oct 2025 11:41
URI: https://eref.uni-bayreuth.de/id/eprint/93170