at Google ScholarTitle data
Jana, Sripati ; Koenigs, Rene M.:
Doyle‐Kirmse Rearrangement Reactions of Difluoroacetates.
In: Asian Journal of Organic Chemistry.
Vol. 8
(2019)
.
- pp. 683-686.
ISSN 2193-5815
DOI: https://doi.org/10.1002/ajoc.201900099
Abstract in another language
In this report, we describe an application of ethyl difluoroacetate-substituted allylic sulfides in Doyle-Kirmse rearrangement reactions that allow efficient access to valuable fluorinated small molecules with applications in total synthesis and drug discovery. A cheap and readily available rhodium catalyst or – in a metal-free variant – visible light was used to generate a carbene intermediate to access rearrangement reactions in high yield.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 02 Apr 2025 12:49 |
| Last Modified: | 14 May 2025 07:54 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93177 |