at Google ScholarTitle data
Empel, Claire ; Hock, Katharina J. ; Koenigs, Rene M.:
Dealkylative intercepted rearrangement reactions of sulfur ylides.
In: Chemical Communications.
Vol. 55
(2019)
.
- pp. 338-341.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C8CC08821G
Abstract in another language
Sulfur ylides are well-known to undergo sigmatropic rearrangement reaction. Herein, we describe a novel reactivity of sulfur ylides, which provides access to the product of a formal functional group metathesis upon dealkylative interception of the rearrangement process. Using a simple iron catalyst and in situ generated diazoalkanes this method provides access to α-mercaptoacetonitrile derivatives.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 02 Apr 2025 12:55 |
| Last Modified: | 07 Oct 2025 11:38 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93179 |