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Iron-catalysed carbene-transfer reactions of diazo acetonitrile

Title data

Empel, Claire ; Hock, Katharina J. ; Koenigs, Rene M.:
Iron-catalysed carbene-transfer reactions of diazo acetonitrile.
In: Organic & Biomolecular Chemistry. Vol. 16 (2018) . - pp. 7129-7133.
ISSN 1477-0539
DOI: https://doi.org/10.1039/C8OB01991F

Abstract in another language

A continuous-flow protocol for the synthesis of diazo acetonitrile was developed. It was further applied in iron-catalysed insertion reactions of diazo acetonitrile into N–H and S–H bonds to yield valuable α-substituted acetonitrile, including gram-scale synthesis.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 02 Apr 2025 13:03
Last Modified: 08 Oct 2025 06:58
URI: https://eref.uni-bayreuth.de/id/eprint/93181