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Cyanomethyl anion transfer reagents for diastereoselective Corey–Chaykovsky cyclopropanation reactions

Title data

Hommelsheim, Renè ; Hock, Katharina J. ; Schumacher, Christian ; Hussein, Mohanad A. ; Nguyen, Thanh V. ; Koenigs, Rene M.:
Cyanomethyl anion transfer reagents for diastereoselective Corey–Chaykovsky cyclopropanation reactions.
In: Chemical Communications. Vol. 54 (2018) . - pp. 11439-11442.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C8CC05602A

Abstract in another language

A readily available and bench-stable cyanomethyl sulfonium salt was used in highly diastereoselective Corey–Chaykovsky cyclopropanation reactions of electron-poor olefins. This efficient method provides a rapid route to access densely functionalized cyclopropyl nitriles.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 02 Apr 2025 13:07
Last Modified: 14 May 2025 07:54
URI: https://eref.uni-bayreuth.de/id/eprint/93182