Title data
Lunkenbein, Thomas ; Girgsdies, Frank ; Wernbacher, Anna ; Noack, Johannes ; Auffermann, Gudrun ; Yasuhara, Akira ; Klein-Hoffmann, Achim ; Ueda, Wataru ; Eichelbaum, Maik ; Trunschke, Annette ; Schlögl, Robert ; Willinger, Marc G.:
Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed Oxide.
In: Angewandte Chemie International Edition.
Vol. 54
(2015)
Issue 23
.
- pp. 6828-6831.
ISSN 1521-3773
DOI: https://doi.org/10.1002/anie.201502236
Abstract in another language
Complex Mo,V-based mixed oxides that crystallize in the orthorhombic M1-type structure are promising candidates for the selective oxidation of small alkanes. The oxygen sublattice of such a complex oxide has been studied by annular bright field scanning transmission electron microscopy. The recorded micrographs directly display the local distortion in the metal oxygen octahedra. From the degree of distortion we are able to draw conclusions on the distribution of oxidation states in the cation columns at different sites. The results are supported by X-ray diffraction and electron paramagnetic resonance measurements that provide integral details about the crystal structure and spin coupling, respectively.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Additional notes: | WOS:000355314100025 |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Operando-Analytics of Electrochemical Energy Storage > Chair Operando-Analytics of Electrochemical Energy Storage - Univ.-Prof. Dr. Thomas Lunkenbein Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Operando-Analytics of Electrochemical Energy Storage |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 12 Jun 2025 11:07 |
| Last Modified: | 04 Jul 2025 11:32 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93736 |

at Google Scholar