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Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed Oxide

Title data

Lunkenbein, Thomas ; Girgsdies, Frank ; Wernbacher, Anna ; Noack, Johannes ; Auffermann, Gudrun ; Yasuhara, Akira ; Klein-Hoffmann, Achim ; Ueda, Wataru ; Eichelbaum, Maik ; Trunschke, Annette ; Schlögl, Robert ; Willinger, Marc G.:
Direct Imaging of Octahedral Distortion in a Complex Molybdenum Vanadium Mixed Oxide.
In: Angewandte Chemie International Edition. Vol. 54 (2015) Issue 23 . - pp. 6828-6831.
ISSN 1521-3773
DOI: https://doi.org/10.1002/anie.201502236

Abstract in another language

Complex Mo,V-based mixed oxides that crystallize in the orthorhombic M1-type structure are promising candidates for the selective oxidation of small alkanes. The oxygen sublattice of such a complex oxide has been studied by annular bright field scanning transmission electron microscopy. The recorded micrographs directly display the local distortion in the metal oxygen octahedra. From the degree of distortion we are able to draw conclusions on the distribution of oxidation states in the cation columns at different sites. The results are supported by X-ray diffraction and electron paramagnetic resonance measurements that provide integral details about the crystal structure and spin coupling, respectively.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: WOS:000355314100025
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Operando-Analytics of Electrochemical Energy Storage > Chair Operando-Analytics of Electrochemical Energy Storage - Univ.-Prof. Dr. Thomas Lunkenbein
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Operando-Analytics of Electrochemical Energy Storage
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 12 Jun 2025 11:07
Last Modified: 04 Jul 2025 11:32
URI: https://eref.uni-bayreuth.de/id/eprint/93736