Title data
Lunkenbein, Thomas ; Schumann, Julia ; Behrens, Malte ; Schlögl, Robert ; Willinger, Marc G.:
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al₂O₃ Catalysts Induced by Strong Metal-Support Interactions.
In: Angewandte Chemie International Edition.
Vol. 54
(2015)
Issue 15
.
- pp. 4544-4548.
ISSN 1521-3773
DOI: https://doi.org/10.1002/anie.201411581
Abstract in another language
In industrially relevant Cu/ZnO/Al2O3 catalysts for methanol synthesis, the strong metal support interaction between Cu and ZnO is known to play a key role. Here we report a detailed chemical transmission electron microscopy study on the nanostructural consequences of the strong metal support interaction in an activated high-performance catalyst. For the first time, clear evidence for the formation of metastable graphite-like ZnO layers during reductive activation is provided. The description of this metastable layer might contribute to the understanding of synergistic effects between the components of the Cu/ZnO/Al2O3 catalysts.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Additional notes: | WOS:000352497600024 |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Operando-Analytics of Electrochemical Energy Storage > Chair Operando-Analytics of Electrochemical Energy Storage - Univ.-Prof. Dr. Thomas Lunkenbein |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 12 Jun 2025 10:55 |
| Last Modified: | 04 Jul 2025 11:32 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93738 |

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