Quick atom transfer radical polymerization of N,N-diisopropyl ammonium acrylate in the presence of air

Title data

Kazemi, Abbass ; Agarwal, Seema ; Greiner, Andreas:
Quick atom transfer radical polymerization of N,N-diisopropyl ammonium acrylate in the presence of air.
In: Designed Monomers and Polymers. Vol. 8 (2005) Issue 6 . - pp. 673-678.
ISSN 1568-5551
DOI: https://doi.org/10.1163/156855505774597731

Official URL:

Abstract in another language

The atom transfer radical polymerization of N,N-diisopropyl ammonium acrylate was successfully carried out, either with continuous exposure to air or in the presence of small amounts of air, which were introduced to the reaction mixture during the polymerization. A linear growth of molecular weight as a function of conversion and low polydispersities of the polymers synthesised here were consistent with the controlled polymerization. Since the polymerization was carried out in the presence of air, oxygen may act as co-catalyst or can be an initiator in a CuBr/bipy/O-2 complex.

Further data

Item Type:	Article in a journal
Refereed:	Yes
Keywords:	polymerization; ATRP; air; acrylate
Institutions of the University:	Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Result of work at the UBT:	No
DDC Subjects:	500 Science > 540 Chemistry
Date Deposited:	13 Apr 2015 08:59
Last Modified:	13 Apr 2015 08:59
URI:	https://eref.uni-bayreuth.de/id/eprint/9709