at Google ScholarTitle data
Agarwal, Seema ; Brandukova-Szmikowski, Natalia E. ; Greiner, Andreas:
Samarium(III)-mediated graft polymerization of ϵ-caprolactone and L-lactide on functionalized poly(p-xylylene)s: Model studies and polymerizations.
In: Polymers for Advanced Technologies.
Vol. 10
(1999)
Issue 9
.
- pp. 528-534.
ISSN 1099-1581
DOI: https://doi.org/10.1002/(SICI)1099-1581(199909)10:9<528::AID-PAT905>3.0.CO;2-3
Abstract in another language
The reductive coupling of ar aromatic monocarbonyl compounds in the presence of SmI2 results in the formation of Samarium(lll) dialkoxides. These Sm(III) dialkoxides have been utilized as initiators fbr ring opening polymerization (ROP) of lactones and lactides. The reductive coupling of aromatic dicarbonyl compounds results in the formation of Sm(III) polyalkoxides which have been used as polyinitiator for (ROP) of lactones and lactides. The products of this process are poly(p-xylylene)s grafted by polylactones or polylactides. Grafting efficiency depends significantly on reaction conditions and is currently limited to 28%. Copyright (C) 1999 John Wiley & Sons, Ltd.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | samarium; PPX; lactone; lactide; graft copolymer |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 10 Apr 2015 09:52 |
| Last Modified: | 24 Feb 2022 13:45 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/9868 |