Crystal structures of the samarium amido complexes [Sm(l-X){N(SiMe₃)₂}₂(THF)]₂ with X=Cl, Br

Title data

Karl, Marc ; Seybert, Gert ; Massa, Werner ; Agarwal, Seema ; Greiner, Andreas ; Dehnicke, Kurt:
Crystal structures of the samarium amido complexes [Sm(l-X){N(SiMe₃)₂}₂(THF)]₂ with X=Cl, Br.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 625 (1999) Issue 9 . - pp. 1405-1407.
ISSN 1521-3749
DOI: https://doi.org/10.1002/(SICI)1521-3749(199909)625:9<1405::AID-ZAAC1405>3.0.CO;2-5

Official URL:

Abstract in another language

The crystal structures of the title compounds have been determined by X-ray methods. Sm(mu-Cl) . {N(SiMe3)(2)}(2)(THF)](2) (1): Space group P2(1)/n, Z = 2, lattice dimensions at 223 K: a = 1429.5(2), b = 1302.3(3), c = 1658.6(3) pm, beta = 114.212(10)degrees, R = 0.0561. Sm(mu-Br) . {N(SiMe3)(2)}(2)(THF)](2) (2): Space group Pbca, Z = 4, lattice dimensions at 223 K: a = 1850.0(7), b = 1611.0(9), c = 1888.1(6) pm, R = 0.0497.

Further data

Item Type:	Article in a journal
Refereed:	Yes
Keywords:	samarium; amido complexes; crystal structures
Institutions of the University:	Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Result of work at the UBT:	No
DDC Subjects:	500 Science > 540 Chemistry
Date Deposited:	08 Apr 2015 10:19
Last Modified:	06 Apr 2023 07:36
URI:	https://eref.uni-bayreuth.de/id/eprint/9869