Flash Communication : An Atomically Dispersed Cu Photocatalyst for the Synthesis of Trifluoromethylated Ferrocenes

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Ludwig, Corentin ; Pradhan, Suman ; Lomas Neff, Alba ; Das, Shoubhik ; Cariou, Kevin ; Gasser, Gilles:
Flash Communication : An Atomically Dispersed Cu Photocatalyst for the Synthesis of Trifluoromethylated Ferrocenes.
In: Organometallics. (22 Juni 2026) .
ISSN 1520-6041
DOI: https://doi.org/10.1021/acs.organomet.6c00140

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Abstract

A recently developed photocatalytic trifluoromethylation method, with the atomically dispersed photocatalyst Cu-@f-gC3N4 and Togni I reagent as a −CF3 source, was optimized for the functionalization of ferrocene. This photocatalytic reaction proceeded at room temperature under visible-light irradiation, and this functionalization remained compatible with functional groups such as ether and halogens.