Adjusting the Composition of Novel Earth-Abundant Transition Metal-Based Oxide Nanoparticles for Electrocatalytic Oxygen Evolution Reaction

Title data

Wölfel, Julia P. ; Marschall, Roland:
Adjusting the Composition of Novel Earth-Abundant Transition Metal-Based Oxide Nanoparticles for Electrocatalytic Oxygen Evolution Reaction.
In: ChemSusChem. Vol. 19 (2026) . - e70880.
ISSN 1864-564X
DOI: https://doi.org/10.1002/cssc.70880

Official URL:

Abstract in another language

To produce green hydrogen through water electrolysis, highly efficient catalysts that use inexpensive, earth-abundant materials are required. In search of novel and inexpensive electrocatalysts, we investigate the adjustment of the composition of transition metal-based catalysts for the alkaline oxygen evolution reaction (OER) and evaluate the effects of both redox-active and -inactive elements. Based on the known synthesis of AFe2O4-type spinels (A?=?transition metal cation), we adjusted the composition of the A and B positions (B?=?Fe position), achieving a significant improvement in catalytic activity. Additionally, we are investigating the high-entropy effect, which is expected to enhance the activity and stability of electrocatalysts. Introducing cobalt and manganese and combining these elements with nickel and zinc formed a NiO/(NiZn)(MnCoFe)2O4 composite that reduced the overpotential for OER to 360?mV. However, increasing the number of A-cations in the spinel beyond six to reach a high-entropy spinel oxide had no positive effect on the overpotential. In terms of composition, the amount of nickel, and thus NiO, could be reduced to 5%, maintaining low overpotentials. The same applies to the proportion of cobalt, which does not scale linearly with activity.

Further data

Item Type:	Article in a journal
Refereed:	Yes
Keywords:	electrocatalysis; high-entropy; oxygen evolution; spinel; transition metals
Institutions of the University:	Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry III - Sustainable Materials for Solar Energy Conversion Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry III - Sustainable Materials for Solar Energy Conversion > Chair Physical Chemistry III - Sustainable Materials for Solar Energy Conversion - Univ.-Prof. Dr. Roland Marschall
Result of work at the UBT:	Yes
DDC Subjects:	500 Science > 540 Chemistry
Date Deposited:	30 Jul 2026 07:37
Last Modified:	30 Jul 2026 07:37
URI:	https://eref.uni-bayreuth.de/id/eprint/99145