at Google ScholarTitle data
Wrackmeyer, Bernd ; Klimkina, Elena V. ; Milius, Wolfgang:
1,3‐Bis(trimethylsilyl)‐1,3,2‐diazaphospha‐[3]ferrocenophanes.
In: Zeitschrift für anorganische und allgemeine Chemie.
Vol. 636
(April 2010)
Issue 5
.
- pp. 784-794.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.200900494
Abstract in another language
The 2-tert-butyl, 2-phenoxy, and 2-diethylamino derivatives of 1,3-bis(trimethylsilyl)-1,3,2-diazaphospha-[3]ferrocenophane were prepared, and the molecular structure of the latter was determined by X-ray diffraction. The phosphines could be oxidized by their slow reactions with sulfur or selenium, and the molecular structures of three sulfides and one selenide were determined. In contrast, the synthesis of oxides was less straightforward. All new compounds were characterized in solution by multinuclear magnetic resonance methods (1D and 2D 1H, 13C, 15N, 29Si, 31P, and 77Se NMR spectroscopy).
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Ferrocenes; Ferrocenophanes; Aminophosphines; NMR spectroscopy; X-ray diffraction |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I > Chair Inorganic Chemistry I - Univ.-Prof. Dr. Josef Breu Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 22 Mar 2018 14:49 |
| Last Modified: | 22 Mar 2018 14:49 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/9919 |