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Ammonolysis of 1,2‐Bis[dichloro(methyl)silyl]ethane : On the Structure of 1,3,6,8‐Tetramethyl‐2,7,11,12‐tetraaza‐1,3,6,8‐tetrasila‐tricyclo[6.2.1.1³,⁶]‐dodecane

Title data

Motz, Günter ; Schmalz, Thomas ; Glatz, Germund ; Kempe, Rhett ; Milius, Wolfgang ; Wrackmeyer, Bernd:
Ammonolysis of 1,2‐Bis[dichloro(methyl)silyl]ethane : On the Structure of 1,3,6,8‐Tetramethyl‐2,7,11,12‐tetraaza‐1,3,6,8‐tetrasila‐tricyclo[6.2.1.1³,⁶]‐dodecane.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 636 (2010) Issue 6 . - pp. 1056-1060.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.200900553

Abstract in another language

Ammonolysis of 1,2-bis[dichloro(methyl)silyl]ethane afforded a crystalline tricyclic silazane along with polymeric material. The crystalline material could be isolated in pure state. It was analyzed by 1H, 13C, 15N and 29Si NMR spectroscopy in solution, by 13C, 15N and 29Si MAS NMR spectroscopy in the solid state, as well as by single-crystal and powder X-ray diffraction. The title compound exists as a single isomer in solution, whereas in the solid state the presence of several modifications is indicated, in particular by the solid-state MAS NMR spectra.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Silazanes; Ammonolysis; Tricycles; X-ray diffraction; NMR spectroscopy
Institutions of the University: Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I > Chair Inorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 23 Mar 2018 07:27
Last Modified: 31 Jan 2022 13:10
URI: https://eref.uni-bayreuth.de/id/eprint/9921