Title data
Nosov, Sergey ; Schmalz, Holger ; Müller, Axel H. E.:
One-pot synthesis of primary amino end-functionalized polymers by reaction of living anionic polybutadienes with nitriles.
In: Polymer.
Vol. 47
(31 May 2006)
Issue 12
.
- pp. 4245-4250.
ISSN 0032-3861
DOI: https://doi.org/10.1016/j.polymer.2006.04.018
Abstract in another language
We present a convenient method to synthesize polymers with primary amino groups by end-capping of living anionic chain ends with nitrites followed by reduction in a one-pot process. As an example, the addition of pivalonitrile to the chain ends of oligobutadienyllithium in toluene, followed by the reduction with sodium borohydride quantitatively leads to omega-amino-oligo-1,4-butadiene, as demonstrated by H-1 and C-13 NMR, thin-layer chromatography and MALDI-ToF mass spectrometry. (c) 2006 Elsevier Ltd. All rights reserved.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Additional notes: | ISI:000238827100001 |
Keywords: | butadiene; anionic polymerization; functionalization |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Profile Fields > Advanced Fields > Polymer and Colloid Science Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Profile Fields Profile Fields > Advanced Fields |
Result of work at the UBT: | Yes |
DDC Subjects: | 500 Science > 540 Chemistry |
Date Deposited: | 16 Apr 2015 05:36 |
Last Modified: | 16 Apr 2015 05:36 |
URI: | https://eref.uni-bayreuth.de/id/eprint/10399 |