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Transport Phenomena, Evaporation, and Thermal Stability of Supported Ionic Liquids

Title data

Heym, Florian ; Kern, Christoph ; Thiessen, Johannes ; Jess, Andreas:
Transport Phenomena, Evaporation, and Thermal Stability of Supported Ionic Liquids.
In: Fehrmann, Rasmus (Hrsg.): Supported Ionic Liquids : Fundamentals and Applications. - Weinheim : Wiley-VCH Verlag , 2014 . - pp. 105-144
ISBN 978-3-527-65480-2
DOI: https://doi.org/10.1002/9783527654789.ch6

Official URL: Volltext

Abstract in another language

Thermophysical properties such as density, heat capacity, thermal conductivity, viscosity, melting point, solvation properties, mass transport properties in/of ILs, thermal stability, and vapor pressure are important for the development and design of supported ionic liquid (IL) processes -. This chapter focuses on the three last-mentioned properties. Diffusion of (dissolved) gaseous, or liquid reactants in the IL layer plays an important role if supported ILs are used to immobilize homogeneous catalysts or to coat heterogeneous catalysts, and may have an influence on the effective reaction rate. The chapter proposes a strategy to determine the vapor pressure and the rate constant of thermal decomposition of ILs.

Further data

Item Type: Article in a book
Refereed: Yes
Keywords: BET equation; ionic liquid; thermogravimetric analysis; thermal decomposition; high vaccum; evaporation; vapor pressure; kinetics; Sherwood-number; thermogravimetry; magnetic suspension balance; BET; fixed bed; SCILL; SILP; supported IL
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Chemical Engineering
Faculties > Faculty of Engineering Science > Chair Chemical Engineering > Chair Chemical Engineering - Univ.-Prof. Dr.-Ing. Andreas Jess
Faculties
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
600 Technology, medicine, applied sciences > 600 Technology
600 Technology, medicine, applied sciences > 620 Engineering
600 Technology, medicine, applied sciences > 660 Chemical engineering
Date Deposited: 26 May 2015 08:56
Last Modified: 26 May 2015 08:56
URI: https://eref.uni-bayreuth.de/id/eprint/14234