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Thermally stable bis(trifluoromethylsulfonyl)imide salts and their mixtures

Title data

Scheuermeyer, Marlene ; Kusche, Matthias ; Agel, Friederike ; Schreiber, Patrick ; Maier, Florian Johannes ; Steinrück, Hans-Peter ; Davis, James H. ; Heym, Florian ; Jess, Andreas ; Wasserscheid, Peter:
Thermally stable bis(trifluoromethylsulfonyl)imide salts and their mixtures.
In: New Journal of Chemistry. Vol. 40 (2016) Issue 8 . - pp. 7157-7161.
ISSN 1144-0546
DOI: https://doi.org/10.1039/C6NJ00579A

Abstract in another language

We show that both tetraphenylphosphonium bis(trifluoromethylsulfonyl)imide ([PPh4][NTf2]) and Cs[NTf2] are low melting salts of exceptionally high and also very similar thermal stability. This similarity indicates that the thermal stability is dominated by the anion. Moreover, eutectic mixtures of [PPh4][NTf2] and Cs[NTf2] with melting points below 100 [degree]C are presented. Surface analysis of the latter in the liquid state reveals a surprising depletion of [PPh4]+ ions from the surface.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Chemical Engineering
Faculties > Faculty of Engineering Science > Chair Chemical Engineering > Chair Chemical Engineering - Univ.-Prof. Dr.-Ing. Andreas Jess
Faculties
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
600 Technology, medicine, applied sciences > 600 Technology
600 Technology, medicine, applied sciences > 620 Engineering
600 Technology, medicine, applied sciences > 660 Chemical engineering
Date Deposited: 11 Aug 2016 06:39
Last Modified: 11 Apr 2018 12:22
URI: https://eref.uni-bayreuth.de/id/eprint/34087