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Selectivity-Enhancing Effect of a SCILL Catalyst in Butadiene Hydrogenation

Title data

Barth, Theresa ; Korth, Wolfgang ; Jess, Andreas:
Selectivity-Enhancing Effect of a SCILL Catalyst in Butadiene Hydrogenation.
In: Chemical Engineering & Technology. Vol. 40 (2017) Issue 2 . - pp. 395-404.
ISSN 1521-4125
DOI: https://doi.org/10.1002/ceat.201600140

Official URL: Volltext

Abstract in another language

Directing the selectivity towards one particular product in a series of consecutive reactions is challenging. Solid catalysts with an ionic liquid layer (SCILL) can be a tool to get a high selectivity of a desired intermediate. For the hydrogenation of butadiene, SCILL catalysts with palladium as active metal yield butene selectivities of up to 99 % even for full conversion of butadiene. Experimental results are presented which corroborate that the SCILL effect is mainly explained by competitive adsorption.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Ionic liquids; SCILL catalyst; SCILL effect; Selective hydrogenation
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Chemical Engineering
Faculties > Faculty of Engineering Science > Chair Chemical Engineering > Chair Chemical Engineering - Univ.-Prof. Dr.-Ing. Andreas Jess
Faculties
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
600 Technology, medicine, applied sciences > 600 Technology
600 Technology, medicine, applied sciences > 620 Engineering
600 Technology, medicine, applied sciences > 660 Chemical engineering
Date Deposited: 09 May 2017 09:02
Last Modified: 09 May 2017 09:02
URI: https://eref.uni-bayreuth.de/id/eprint/37084