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Cyclometalated Pt complex-based random terpolymers for efficient polymer solar cells

Title data

Wang, Zheng ; Yang, Jie ; Liu, Yanan ; Wang, Shifan ; Zhong, Yu ; Li, Cheng ; Zhang, Zhiguo ; Xing, Guichuan ; Hüttner, Sven ; Tao, Youtian ; Li, Yongfang ; Huang, Wei:
Cyclometalated Pt complex-based random terpolymers for efficient polymer solar cells.
In: Polymer Chemistry. Vol. 8 (2017) Issue 32 . - pp. 4729-4737.
ISSN 1759-9954
DOI: https://doi.org/10.1039/C7PY00924K

Abstract in another language

Platinum complex was introduced in low ratios (0, 1, 1.5, and 5 mol) as the third monomer in the conjugated backbone of well-known donor polymer PTB7-Th using a random terpolymer molecular design approach. All polymers showed similar absorption behavior and comparable HOMO/LUMO energy levels due to the small amount of Pt complex used. When blended with PC71BM in polymer solar cells, the power conversion efficiency was enhanced to 8.45 (obtained by the device based on PTB7-ThPt1.5 containing 1.5 mol Pt) compared with 7.92 for the control PTB7-Th. Notably, the apparently low molecular weight of PTB7-ThPt1.5 (Mn/Mw: 46/70 kg mol-1) compared with that of PTB7-Th (Mn/Mw: 62/97 kg mol-1) ensured a more convincing comparison. Using a combination of physical measurements, such as optoelectrical characterization, grazing incident wide-angle X-ray diffraction (GIWAXS), and picosecond time-resolved photoluminescence, the efficiency enhancement was contributed by the higher hole mobility, less bimolecular recombination, and a more efficient slow charge separation process.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Junior Professorship Solar Energy > Junior Professorship Solar Energy - Juniorprof. Dr. Sven Hüttner
Profile Fields > Advanced Fields > Polymer and Colloid Science
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Junior Professorship Solar Energy
Profile Fields
Profile Fields > Advanced Fields
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 530 Physics
500 Science > 540 Chemistry
Date Deposited: 30 Aug 2017 06:03
Last Modified: 30 Aug 2017 06:03
URI: https://eref.uni-bayreuth.de/id/eprint/39199