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N-Heteroacenes as a New Class of Non-Fullerene Electron Acceptors for Organic Bulk-Heterojunction Photovoltaic Devices

Titelangaben

Lami, Vincent ; Leibold, David ; Fassl, Paul ; Hofstetter, Yvonne J. ; Becker-Koch, David ; Biegger, Philipp ; Paulus, Fabian ; Hopkinson, Paul E. ; Adams, Michael ; Bunz, Uwe H. F. ; Hüttner, Sven ; Howard, Ian ; Bakulin, Artem A. ; Vaynzof, Yana:
N-Heteroacenes as a New Class of Non-Fullerene Electron Acceptors for Organic Bulk-Heterojunction Photovoltaic Devices.
In: Solar RRL. Bd. 1 (2017) Heft 6 . - Art.Nr. 1700053.
ISSN 2367-198X
DOI: 10.1002/solr.201700053

Abstract

Herein, we present the first investigation of N-heteroacenes as acceptors in bulk-heterojunction solar cells. The optical and electronic properties of tetraazapentacene (TIPS-TAP), triptycenyl-tetraazapentacene (TIPS-TAP-1T), and bistriptycenyl-tetraazapentacene (TIPS-TAP-2T) compounds are characterized by UV-vis, photothermal deflection, and ultraviolet photoemission spectroscopies. We compare the photovoltaic performance of the N-heteroacenes and find that cells with TIPS-TAP-2T significantly outperform the other derivatives, achieving a power conversion efficiency of 2.5 without extensive optimization or processing additives. We characterize the morphology and order within the active layer by atomic force microscopy and grazing incidence wide-angle scattering measurements, and find that blends with TIPS-TAP result in a gross phase separation driven by its strong crystallization. The substitution with triptycenyl units suppresses this crystallization resulting in amorphous films with a finer intermixing and a smooth surface structure. Finally, we investigate the photophysics of charge separation at the donor/acceptor interface and find that it is fundamentally different from the “conventional” polymer-fullerene systems. In blends with the tetraazapentacene derivatives, exciton dissociation is relatively slow and charge separation is strongly field dependent. We observe improved charge generation and significantly reduced recombination for TIPS-TAP-2T as compared to the other derivatives, which in combination with the improved film microstructure is responsible for the enhanced photovoltaic performance.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Juniorprofessur Solarenergie > Juniorprofessur Solarenergie - Juniorprof. Dr. Sven Hüttner
Profilfelder > Advanced Fields > Polymer- und Kolloidforschung
Fakultäten
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Juniorprofessur Solarenergie
Profilfelder
Profilfelder > Advanced Fields
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 530 Physik
500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 04 Sep 2017 13:51
Letzte Änderung: 04 Sep 2017 13:51
URI: https://eref.uni-bayreuth.de/id/eprint/39263