bei Google ScholarTitelangaben
Wu, Qingjing ; Cheng, Yang ; Xue, Zhongyuan ; Gao, Xuyu ; Wang, Menghan ; Yuan, Wenbo ; Hüttner, Sven ; Wan, Shigang ; Cao, Xudong ; Tao, Youtian ; Huang, Wei:
A cyclometalating organic ligand with an Iridium center toward dramatically improved photovoltaic performance in organic solar cells.
In: Chemical Communications.
Bd. 55
(2019)
Heft 18
.
- S. 2640-2643.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C9CC00173E
Abstract
Organometallic compounds as photoactive materials are relatively new in organic solar cells. Upon cyclometalation, the octahedral heteroleptic Ir complex TBzIr exhibits significantly enhanced optical-absorption and improved film-morphology compared to the planar organic 2-(5′′-hexyl-2{,}2′:5′{,}2′′-terthiophen-5-yl)benzodthiazole (TBz) ligand. Thus{,} a dramatically improved power conversion efficiency (PCE) from ∼0 to 3.81% is attained when combined with PC71BM.