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Theoretical and Experimental Study of Monofunctional Vinyl Cyclopropanes Bearing Hydrogen Bond Enabling Side Chains

Title data

Schumacher, Sören ; Pantawane, Sanwardhini ; Gekle, Stephan ; Agarwal, Seema:
Theoretical and Experimental Study of Monofunctional Vinyl Cyclopropanes Bearing Hydrogen Bond Enabling Side Chains.
In: Macromolecules. (January 2021) .
ISSN 0024-9297
DOI: https://doi.org/10.1021/acs.macromol.0c02490

Project information

Project financing: Deutsche Forschungsgemeinschaft
VolkswagenStiftung

Abstract in another language

The synthesis of four different monofunctional vinyl cyclopropane (VCP) derivatives and their polymerization behavior is presented. The different VCPs have different capabilities to form hydrogen bonds in their side chain. A preorganization due to these hydrogen bonds should lead to a fast polymerization. Kinetic studies, hydrogen-bond strength, and theoretical calculations were used to correlate the degree of conversion and the amount of preorganization. While VCPs capable of hydrogen bonding did not show a huge difference, a general effect of hydrogen bonds on polymerization behavior could be observed.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Vinyl cyclopropane; Radical ring-opening polymerization; Hydrogen bonding; Preorganization
Institutions of the University: Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Professor Theoretical Physics VI - Simulation and Modelling of Biofluids > Professor Theoretical Physics VI - Simulation and Modelling of Biofluids - Univ.-Prof. Dr. Stephan Gekle
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Profile Fields > Advanced Fields > Polymer and Colloid Science
Research Institutions > Affiliated Institutes > Bavarian Polymer Institute (BPI)
Faculties
Faculties > Faculty of Mathematics, Physics und Computer Science
Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics
Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Professor Theoretical Physics VI - Simulation and Modelling of Biofluids
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Profile Fields
Profile Fields > Advanced Fields
Research Institutions
Research Institutions > Affiliated Institutes
Result of work at the UBT: Yes
DDC Subjects: 500 Science
500 Science > 530 Physics
500 Science > 540 Chemistry
Date Deposited: 11 Jan 2021 13:18
Last Modified: 11 Jan 2021 14:28
URI: https://eref.uni-bayreuth.de/id/eprint/61551