Literatur vom gleichen Autor/der gleichen Autor*in
plus bei Google Scholar

Bibliografische Daten exportieren
 

Platinum Nanostructure Tailoring for Fuel Cell Applications Using Levitated Water Droplets as Green Chemical Reactors

Titelangaben

El-Nagar, Gumaa A. ; Delikaya, Öznur ; Lauermann, Iver ; Roth, Christina:
Platinum Nanostructure Tailoring for Fuel Cell Applications Using Levitated Water Droplets as Green Chemical Reactors.
In: ACS Applied Materials & Interfaces. Bd. 11 (2019) Heft 25 . - S. 22398-22407.
ISSN 1944-8252
DOI: https://doi.org/10.1021/acsami.9b05156

Abstract

Tailoring of nanostructured materials with well-controlled morphologies and their integration into valuable applications in a facile, cheap, and green way remain a key challenge. Herein, platinum nanoparticles as well as Pt–polymer nanocomposites with unique shapes, including flower-, needle-, porous-, and worm-like structures, were synthesized and simultaneously deposited on a three-dimensional carbon substrate and carbon nanofibers in one step using a levitated, overheated water drop as a green, rotating chemical reactor. Sprinkling of a metal aqueous solution on a hot surface results in its sudden evaporation and creates an overheated zone along with the water self-ionization (i.e., charge separation) at the hot interface. These generated Leidenfrost conditions are believed to induce a series of chemical reactions involving the used solvent and counterions, resulting in the nanoparticles formation. Besides, the in situ generated basic conditions in the vicinity of the liquid–vapor interface due to the loss of hydronium ions into the vapor layer could also play a role in the mechanism of the nanoparticles formation, e.g., by discharging. The as-prepared Pt nanostructures exhibited a superior catalytic activity and stability toward the desired direct formic acid oxidation (essential anodic reaction in fuel cells) into CO2 without generating CO poisoning intermediates compared to the state-of-the-art commercial PtC electrode. The addressed nanotailoring technique is believed to be a promising, inexpensive, and scalable way for the sustainable manufacture of well-designed nanomaterials for future applications.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Keywords: nanostructures; fuel cells; electrocatalysis; Leidenfrost; green chemistry
Institutionen der Universität: Fakultäten > Fakultät für Ingenieurwissenschaften > Lehrstuhl Werkstoffverfahrenstechnik > Lehrstuhl Werkstoffverfahrenstechnik - Univ.-Prof. Dr. Christina Roth
Fakultäten
Fakultäten > Fakultät für Ingenieurwissenschaften
Fakultäten > Fakultät für Ingenieurwissenschaften > Lehrstuhl Werkstoffverfahrenstechnik
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften
Eingestellt am: 28 Apr 2021 11:09
Letzte Änderung: 28 Apr 2021 11:09
URI: https://eref.uni-bayreuth.de/id/eprint/64974