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Janus Micelles by Crystallization-Driven Self-Assembly of an Amphiphilic, Double-Crystalline Triblock Terpolymer

Title data

Hils, Christian ; Schmelz, Joachim ; Drechsler, Markus ; Schmalz, Holger:
Janus Micelles by Crystallization-Driven Self-Assembly of an Amphiphilic, Double-Crystalline Triblock Terpolymer.
In: Journal of the American Chemical Society. Vol. 143 (2021) Issue 38 . - pp. 15582-15586.
ISSN 1520-5126
DOI: https://doi.org/10.1021/jacs.1c08076

Abstract in another language

Surface-compartmentalized micellar nanostructures (Janus and patchy micelles) have gained increasing interest due to their unique properties opening highly relevant applications, e.g., as efficient particulate surfactants, compatibilizers in polymer blends, or templates for catalytically active nanoparticles. We present a facile method for the production of worm-like Janus micelles based on crystallization-driven self-assembly of a double-crystalline triblock terpolymer with a crystallizable polyethylene middle block and two highly incompatible corona blocks, polystyrene and poly(ethylene oxide). This approach enables the production of amphiphilic Janus micelles with excellent interfacial activity by a comparably simple heating and cooling protocol directly in solution.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Profile Fields > Advanced Fields > Polymer and Colloid Science
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP A 2
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 01 Oct 2021 08:13
Last Modified: 01 Oct 2021 08:13
URI: https://eref.uni-bayreuth.de/id/eprint/67144